High Temperature Protonic Conduction in Aragonite-Type NdBO3

Protonic diffusion in high-pressure ice VII.

Near ambient pressures, molecular diffusion dominates protonic diffusion in ice. Theoretical studies have predicted that protonic diffusion will dominate at high pressures in ice. We measured the protonic diffusion coefficient for the highest temperature molecular phase of ice VII at 400 kelvin over its entire stable pressure region. The values ranged from 10(-17) to 10(-15) square meters per s...

Protonic defects in oxides and their possible role in high temperature oxidation

Protons from hydrogen or water vapour may dissolve in oxides and other corrosion products, and may affect, and in some cases, dominate their defect structures. Defect-dependent properties like scale growth and plastic deformation then become dependent on the ambient hydrogen or water vapour pressure. Small concentrations of protons may enhance the transport of oxygen in the form of hydroxide io...

Impurity band conduction in a high temperature ferromagnetic semiconductor.

The band structure of a prototypical dilute magnetic semiconductor (DMS), Ga1-xMnxAs, is studied across the phase diagram via infrared and optical spectroscopy. We prove that the Fermi energy (EF) resides in a Mn-induced impurity band (IB). Specifically the changes in the frequency dependent optical conductivity [sigma1(omega)] with carrier density are only consistent with EF lying in an IB. Fu...

Temperature Profiles in Hamiltonian Heat Conduction

We study heat transport in the context of Hamiltonian and related stochastic models with nearest-neighbor coupling, and derive a universal law for the temperature profiles of a large class of such models. This law contains a parameter α , and is linear only when α = 1. The value of α depends on energy-exchange mechanisms, including the range of motion of tracer particles and their times of flight.

Corrigendum: H+-type and OH−-type biological protonic semiconductors and complementary devices